GaxN2:Zn3-x薄膜的分子束外延生长及其光学和电子输运性能表征

本文采用分子束外延技术,通过对金属分子束的精确控制,在MgO(002)基底上成功生长了Ga_xN₂∶Zn_3-x合金薄膜.高分辨率单晶X光衍射仪表征结果表明Ga_xN₂∶Zn_3-x合金薄膜仍是以(400)Zn₃N₂为主导的复合晶体结构,对衍射数据的分析得到该薄膜晶粒尺寸小.用扫描电子显微镜和能谱射线分析仪对其表面和成分做了深入的分析和讨论,在固定的金属流量比的生长环境下,不同厚度的样品在成膜后x均为0.65,化学通式Zn_2.35Ga_0.65N₂.该结果表明Ga元素属于重度掺杂,同时也体现了分子束外延技术在共掺杂技术中的优越性.本文也测量并讨论了Zn_2.35Ga_0.65N₂薄膜的光学性能,实验得到的1.85 eV的光学带隙与理论推算基本吻合,说明Ga的掺入有Ga-N结构...     

High quality nitrogen-doped zinc oxide thin films grown on ITO by sol–gel method

Highly transparent N-doped ZnO thin films were deposited on ITO coated corning glass substrate by sol–gel method. Ammonium nitrate was used as a dopant source of N with varying the doping concentration 0, 0.5, 1.0, 2.0 and 3.0 at%. The DSC analysis of prepared NZO sols is observed a phase transition at 150 °C. X-ray diffraction pattern showed the preferred (002) peak of ZnO, which was deteriorated with increased N concentrations. The transmittance of NZO thin films was observed to be ~88%. The bandgap of NZO thin films increased from 3.28 to 3.70 eV with increased N concentration from 0 to 3 at%. The maximum carrier concentration 8.36×10¹⁷ cm⁻³ and minimum resistivity 1.64 Ω cm was observed for 3 at% N doped ZnO thin films deposited on glass substrate. These highly transparent ZnO thin films can be used as a window layer in solar cells and optoelectronic devices.     

Tuning the electronic properties of conjugated polymer by tethering low‐bandgap rhenium(I) complex on the main chain

Low‐bandgap rhenium(I) complex with absorption onset at 795 nm in solution was tethered onto π‐conjugated polymer. The conjugated copolymer provides solution processability of the metallopolymer, and the pendant allows the low energy‐absorbing Re(I) complex units to be evenly distributed on the thin film. The copolymer tethered with low‐bandgap rhenium complex was synthesized by Suzuki cross‐coupling reaction. The metal‐free polymer ( poly‐1 ) tethered with functionalized intramolecular charge transfer dye, 2‐phenyl‐3‐pyridin‐2‐yl‐5,7‐di‐2‐thienylthieno[3,4‐b]pyrazine, exhibited high molecular weight, good film‐forming properties, and excellent solution processability. The pendants of the conjugated polymer possess donor–acceptor characters and broaden the absorption band. These pendants can function as bidentate ligands for metal chelation. The solubilizing groups on the monomers provide good solubility to the polymer even with high content of metal chelation. Upon the complexation with rhenium(I) pentacarbonyl chloride, the absorption spectrum of the resulting metallopolymer was further extended toward the near‐infrared region. Photovoltaic performances based on this metallopolymer have been studied. The design approach of these metallopolymers provides synthetic feasibility for coordinating wide range of metal ions on the pendant, and the resulting low‐bandgap polymer can be a potential candidate for light harvesting material in solar cell applications. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2311–2319, 2010     

Modulation of photonic band structures with dielectric anisotropy

By the multiple scattering method and the extended Mie theory, we have calculated the photonic band structure of the photonic crystals consisting of the dielectric spheres with uniaxial/biaxial anisotropy. The results demonstrate that for fcc lattice structure there exist two partial photonic band gaps which does not appear in the isotropic case. Among them, the lower one, lying between the second and the third bands, exists in one third of the first Brillouin zone, while the upper one, opening between the fourth and fifth bands, can appear simultaneously in the rest two thirds of the first Brillouin zone. The effects of anisotropy on the band structures are studied as well, which suggests the biaxial anisotropy are much more flexible than the uniaxial anisotropy in modulating the band structures.     

用时域有限差分法研究二维光子晶体传输特性

将时域有限差分方法用于光子晶体传输特性理论研究，分别计算了二维方型光子晶体TM模和TE模的透射率频率分布；根据光子晶体的标度不变性特征，在微波频段制作了光子晶体，并设计了实验装置；实验结果与计算结果一致表明：对于一定的入射方向，某些频率的光不能在光子晶体中传播。     

含负折射率材料一维光子晶体的全方位带隙和缺陷模

运用光学传输矩阵理论,研究了含负折射率材料一维二元光子晶体的禁带特性和局域模特性,发现了一种新型全方位光子带隙.与传统的Bragg带隙相比,这种新型全方位光子带隙的中心频率和带宽对入射角的变化不敏感.讨论了引入缺陷层后,入射角变化和各层介质厚度做一定比例的缩放时对缺陷模位置的影响.这种特性在具有固定带宽的全方位反射器和微波技术中全方位或大入射角滤波器方面有重要的应用价值.     

Graphite格子光子晶体带隙的数值模拟

采用平面波展开法模拟计算了由锗圆柱构成的Graphite格子二维光子晶体的带隙结构,发现由空气背景中的介质柱构成的二维Graphite格子结构的光子晶体具有完全光子带隙,并得到了使完全带隙最大化的结构参数。数值计算结果表明,Graphite结构二维光子晶体在填充比从f=0.058到f=0.605连续变化的很大范围内都有完全带隙出现,在低能区出现了Δ=0.053(ωa/2πc)的较大带隙。     

Omnidirectional Single-negative Gap and in Fibonacci Sequences Composed of Single-negative Materials

The band structures of Fibonacci sequence composed of single-negative materials are studied with a transfer matrix method. A new type of omnidirectional single-negative gaps is found in the Fibonacci sequence. In contrast to the Bragg gaps, such an omnidirectional single-negative gap is insensitive to the incident angles and polarization, and is invariant upon the change of the ratio of the thicknesses of two media. It is found that omnidirectional single-negative gap exists in the other Fibonacci sequence, and it is rather stable and independence of the structure sequence.     

Transmission spectra of films of Mn<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Fe<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Se solid solutions

Films of Mn_1−x Fe _x Se (x = 0–0.45) solid solutions were flash-sputtered. We measured the transmission spectra of the films in the wavelength range 200–1000 nm at room temperature. From these spectra, we calculated the absorption coefficients and determined the fundamental absorption edge, the position of which is shifted from 2.65 eV in MnSe to 2.30 eV in solid solutions of compositions x = 0.20–0.45. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 1, pp. 136–138, January–February, 2007.